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8. Enzymes as catalysts
8.7 Making faded jeans last page page 42
Photo of stone washed jeans
Picture 8.11 Stonewashed jeans.
Jeans made from denim were originally designed as hard wearing trousers for use by cowboys in the USA. They were traditionally dyed with the natural blue dye indigo. This dye, an example of a vat dye, is precipitated within the fibres of the cellulose material during the dyeing process.
Stonewashed jeans . . .
Denim jeans have now, however, become a world wide leisure and fashion item. Some people prefer their jeans to have a worn 'stonewash' appearance. This can be achieved by rotating the fabric in a drum along with some stones. Hence the name stonewash. The stones break some of the fibres and release the indigo dye. The jeans now look faded.
. . . without the stones
An alternative way of fading jeans uses the catalytic ability of the enzyme cellulase. The dyed material is soaked in the enzyme solution. The enzyme catalyses the hydrolysis of the cellulose fibre and so leads to the breakdown of fibres on the surface of the fabric and the subsequent loss of the indigo dye they have encapsulated.
Model of indigo structure
Picture 8.12. A model of indigo. Grey=carbon; white=hydrogen; red=oxygen; blue=nitrogen.
Question 39

What are the advantages of using cellulase to break down cellulose fibres and so fade denim jeans rather than using the abrasion produced by stones in a rotating drum?

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